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Environmental Risks and Damage – Toolbox Talk

02/08/2022 3 min de leitura Safety For Job Team
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Environmental Risks and Damage – All dangerous goods have their physical-chemical characteristics, which produce: EXPLOSIVE, FLAMMABLE, TOXIC, OXIDIZING and RADIOACTIVE.

The danger is related to the state of the product, the risk control measures and the quantities transported. The greater the safety conditions and the greater the knowledge of the employees about the product, as well as the measures to be adopted in case of emergency, the lesser the potential for danger. The risks that basically polarize people’s attention are due to the FLAMMABILITY of dangerous products.

Substances (including mixtures and solutions) and articles subject to this Regulation are allocated to one of nine classes according to the risk or the most serious of the risks they present. Some of these classes are subdivided into subclasses. However, the classification and definition of the classes of dangerous products, as well as the quantities, gaseous concentrations and degree of explosiveness must be considered:

CLASS 1 – EXPLOSIVES

Subclass 1.1: Substances and articles with a mass explosion hazard

Subclass 1.2: Substances and articles with a projection hazard but not a mass explosion hazard.

Subclass 1.3: Substances and articles with a fire hazard and a small explosion or projection hazard, or both, but not a mass explosion hazard.

Subclass 1.4: Substances and articles that do not present a significant risk

Subclass 1.5: Very insensitive substances with a mass explosion hazard

Subclass 1.6: Extremely insensitive articles with no mass explosion hazard

CLASS 2 – COMPRESSED, LIQUEFIED, DISSOLVED UNDER PRESSURE OR HIGHLY REFRIGERATED GASES

Subclass 2.1: Flammable gases

Subclass 2.2: Non-flammable, non-toxic gases

Subclass 2.3: Toxic gases

CLASS 3-FLAMMABLE LIQUIDS

RISK GROUP I- Flammable liquids with flash point
below 23°C in a closed vessel and initial boiling point below or equal to 35°C.

RISK GROUP II – Flammable liquids with a flash point below 23°C in a closed vessel, but with a boiling point greater than 35°C.

RISK GROUP III – Flammable liquids with a flash point equal to or greater than 23°C to 60.5°C in a closed vessel with an initial boiling point greater than 35°C.

CONCLUSION – The lower the flash point, the greater the risk of emitting flammable vapors.

CLASS 4- FLAMMABLE SOLIDS; SUBSTANCES SUBJECT TO SPONTANEOUS COMBUSTION; SUBSTANCES
WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES

Flammable solids; substances subject to spontaneous combustion;

Substances which, in contact with water, emit flammable gases

Subclass 4.1: Flammable solids, self-reactive substances
and desensitized solid explosives

Subclass 4.2: Substances subject to spontaneous combustion

Subclass 4.3: Substances which, in contact with water, emit
flammable gases


CLASS 5 – OXIDIZING SUBSTANCES; PEROXIDES ORGANIC

SUBCLASS 5.1 – Oxidizing substances.

SUBCLASS 5.2- Organic peroxides.

CLASS 6 – INFECTING SUBSTANCES

SUBCLASS 6.1 – Toxic substances: cause death or damage to health in case of ingestion, inhalation or skin contact.

SUBCLASS 6.2 – Infectious substance.

CLASS 7- RADIOACTIVE SUBSTANCES

CLASS 8 – CORROSIVES

GROUP I – Up to 3 minutes: skin necrosis (VERY DANGEROUS).

GROUP II – Causes visible skin necrosis after a contact period of more than 3 minutes but not longer than 60 minutes
(MEDIUM RISK).

GROUP III – Contact period of less than 4 hours (LOWER RISK SUBSTANCES).

CLASSE 9 – SUBSTÂNCIAS PERIGOSAS DIVERSAS


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